Volume 31 Issue 6 2024

Volume 31 Issue 6 2024

Journal of Functional Materials — Research Articles

Serial: 1

Nanoengineering of Soil-Based Materials

Authors: Eva M. Rodriguez, Liam J. Thompson
Page No: 1–6
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—The paper examines the mechanism of pozzolan-soil reactions, using a recent study on the chemical stabilization of a Class A-2-7 (3) lateritic soil, with corn cob ash (CCA) as case study. The objectives are to establish a nexus between cation exchange capacity of the soil, the alkaline forming compounds in CCA and percentage CCA addition to soil beyond which no more improvement in strength properties can be achieved; and to propose feasible chemical reactions to explain the chemical stabilization of the lateritic soil with CCA alone. The lateritic soil, as well as CCA of pozzolanic quality Class C were separately analysed for their metallic oxide composition using the X-Ray Fluorescence technique. The cation exchange capacity (CEC) of the soil and the CCA were computed theoretically using the percentage composition of the base cations Ca2+, Mg2+ K+ and Na2+ as 1.48 meq/100 g and 61.67 meq/100 g respectively, thus indicating a ratio of 0.024 or 2.4%. This figure, taken as the theoretical amount required to just fill up the exchangeable sites of the clay molecules, compares well with the laboratory observation of 1.5% for the optimum level of CCA addition to lateritic soil. The paper went on to present chemical reaction equations between the alkaline earth metals in the CCA and the silica in the lateritic soil to form silicates, thereby proposing an extension of the theory of mechanism of soil stabilization to cover chemical stabilization with pozzolanic ash only. The paper concluded by recommending further research on the molecular structure of soils stabilized with pozzolanic waste ash alone, with a view to confirming the chemical equations advanced in the study. Keywords—Cation exchange capacity, corn cob ash, lateritic soil, soil stabilization. I.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Eva M. Rodriguez, Liam J. Thompson, "Nanoengineering of Soil-Based Materials," Journal of Functional Materials, vol. 31, no. 6, pp. 1–6, 2024.

Serial: 2

Mechanical Properties of Composite Iron Alloys

Authors: Elena Vasquez, Lucas Jensen
Page No: 7–9
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—In this research (using induction furnace process) nodular iron with three different percentages of copper (residual, 0.5% and 1,2%) was obtained. Chemical analysis was performed by mass spectrometry and microstructures were characterized by Optical Microscopy (ASTM E3) and Scanning Electron Microscopy (SEM). The study of mechanical behavior was carried out in a mechanical test machine (ASTM E8) and a Pin on disk tribometer (ASTM G99) was used to assess wear resistance. It is observed that the dissolution of copper in crystal lattice increases the pearlite structure improving the wear and hardness behavior, but producing a contrary effect on the energy absorption. Keywords—Ferritic and perlite structure, mechanical properties, nodular iron, wear. I.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Elena Vasquez, Lucas Jensen, "Mechanical Properties of Composite Iron Alloys," Journal of Functional Materials, vol. 31, no. 6, pp. 7–9, 2024.

Serial: 3

Analysis of Causality between Defect Causes Using Machine Learning

Authors: Eva Morales, Liam Chen
Page No: 10–13
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—Construction defects are major components that result in negative impacts on project performance including schedule delays and cost overruns. Since construction defects generally occur when a few associated causes combine, a thorough understanding of defect causality is required in order to more systematically prevent construction defects. To address this issue, this paper uses association rule mining (ARM) to quantify the causality between defect causes, and social network analysis (SNA) to find indirect causality among them. The suggested approach is validated with 350 defect instances from concrete works in 32 projects in Korea. The results show that the interrelationships revealed by the approach reflect the characteristics of the concrete task and the important causes that should be prevented. Keywords—Causality, defect causes, social network analysis, association rule mining. I.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Eva Morales, Liam Chen, "Analysis of Causality between Defect Causes Using Machine Learning," Journal of Functional Materials, vol. 31, no. 6, pp. 10–13, 2024.

Serial: 4

Advanced Nanostructured Materials for Energy Harvesting

Authors: Evelyn R. Foster, Liam M. Reed
Page No: 14–19
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—The nickel-manganese (Ni-Mn) alloy coating prepared from DC electrodeposition process in sulphamate bath was studied. The effects of process parameters, such as current density and electrolyte composition, on the cathodic current efficiency, microstructure, internal stress and mechanical properties were investigated. Because of its crucial effect on the application to the electroforming of microelectronic components, the development of low internal stress coating with high leveling power was emphasized. It was found that both the coating’s manganese content and the cathodic current efficiency increased with the raise in current density. In addition, the internal stress of the deposited coating showed compressive nature at low current densities while changed to tensile one at higher current densities. Moreover, the metallographic observation, X-ray diffraction measurement, and polarization curve measurement were conducted. It was found that the Ni-Mn coating consisted of nano-sized columnar grains and the maximum hardness of the coating was associated with (111) preferred orientation in the microstructure. The grain size was refined along with the increase in the manganese content of the coating, which accordingly, raised its hardness and resistance to annealing softening. In summary, the Ni- Mn coating prepared at lower current density of 1-2 A/dm2 had low internal stress, high leveling power, and better corrosion resistance. Keywords—DC plating, internal stress, leveling power, Ni-Mn coating. I.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Evelyn R. Foster, Liam M. Reed, "Advanced Nanostructured Materials for Energy Harvesting," Journal of Functional Materials, vol. 31, no. 6, pp. 14–19, 2024.

Serial: 5

Impact Analysis of Holistic Vibration on Cellular Adaptation

Authors: Rohan Vashisht, Aaradhya Kumar
Page No: 20–27
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: A new proprietary herbomineral formulation was formulated, consisting of herbal root extract ashwagandha and minerals (zinc, magnesium, and selenium). The objective of this study was to evaluate the immunomodulatory effect of the Biofield Energy Healing (The Trivedi Effect®) Treatment on the test herbomineral formulation in male Sprague Dawley rats. The test formulation was divided into two parts; one was represented as control, while the other part was treated with the Biofield Energy Healing Treatment by eighteen renowned Biofield Energy Healers and defined as the Biofield Energy Treated formulation. Besides, one group of animals was also received Biofield Energy Treatment by same Biofield Energy Healers under similar conditions. The effect of the test formulation was monitored by an estimation of humoral immune response, delay type hypersensitivity, hematology, biochemistry, body weight, feed intake, relative organ weight, and histopathology in male Sprague Dawley rats. The primary antibody titre level was significantly increased by 36.36% in the Biofield Energy Treated formulation (G3); while decreased by 15.09% in the untreated test formulation (G4) compared to the disease control group (G2). The paw volume was significantly increased by 75% in the Biofield Energy Treated group per se at day -15 (G6) compared to the disease control. The level of red blood corpuscle (RBC) was significantly increased by 14.45% in the G6 group compared to the G2 group. The platelet count was significantly increased by 10.32% in the G3 group; while it was decreased by 5.71% in the G4 group compared with the G2 group. There was a significant elevation of serum phosphorus by 6.04% in the G3 group compared to the G2 group. The concentration of magnesium in serum was increased by 13.00% in the Biofield Energy Treated formulation (G3) compared to the disease control group (G2). The concentration of uric acid was significantly decreased by 8.05% in the Biofield Energy Treated formulation (G3) compared to the G2 group. Further, the change in body weight, feed consumption, organ to body weight ratio data, and histopathology examination did not suggest any statistical difference, which depicts that the Biofield Energy Treated test formulation was found to be safe. These data suggest that the Biofield Treated test formulation can be used for autoimmune and inflammatory diseases such as Rheumatoid arthritis, Alzheimer’s disease, Atherosclerosis, Dermatitis, Diverticulitis, Diabetes, etc. along with stress prevention and management and anti-aging by improving overall health.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Rohan Vashisht, Aaradhya Kumar, "Impact Analysis of Holistic Vibration on Cellular Adaptation," Journal of Functional Materials, vol. 31, no. 6, pp. 20–27, 2024.

Serial: 6

Advanced Nanostructured Catalysts for Microbial Fuel Cells

Authors: Aisha Fatima, Liam Ryan
Page No: 28–34
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—Microbial fuel cells (MFCs) represent a promising technology for simultaneous bioelectricity generation and wastewater treatment. Catalysts are significant portions of the cost of microbial fuel cell cathodes. Many materials have been tested as aqueous cathodes, but air-cathodes are needed to avoid energy demands for water aeration. The sluggish oxygen reduction reaction (ORR) rate at air cathode necessitates efficient electrocatalyst such as carbon supported platinum catalyst (Pt/C) which is very costly. Manganese oxide (MnO2) was a representative metal oxide which has been studied as a promising alternative electrocatalyst for ORR and has been tested in air-cathode MFCs. However the single MnO2 has poor electric conductivity and low stability. In the present work, the MnO2 catalyst has been modified by doping Pt nanoparticle. The goal of the work was to improve the performance of the MFC with minimum Pt loading. MnO2 and Pt nanoparticles were prepared by hydrothermal and sol gel methods, respectively. Wet impregnation method was used to synthesize Pt/MnO2 catalyst. The catalysts were further used as cathode catalysts in air-cathode cubic MFCs, in which anaerobic sludge was inoculated as biocatalysts and palm oil mill effluent (POME) was used as the substrate in the anode chamber. The asprepared Pt/MnO2 was characterized comprehensively through field emission scanning electron microscope (FESEM), X-Ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV) where its surface morphology, crystallinity, oxidation state and electrochemical activity were examined, respectively. XPS revealed Mn (IV) oxidation state and Pt (0) nanoparticle metal, indicating the presence of MnO2 and Pt. Morphology of Pt/MnO2 observed from FESEM shows that the doping of Pt did not cause change in needle-like shape of MnO2 which provides large contacting surface area. The electrochemical active area of the Pt/MnO2 catalysts has been increased from 276 to 617 m2/g with the increase in Pt loading from 0.2 to 0.8 wt%. The CV results in O2 saturated neutral Na2SO4 solution showed that MnO2 and Pt/MnO2 catalysts could catalyze ORR with different catalytic activities. MFC with Pt/MnO2 (0.4 wt% Pt) as air cathode catalyst generates a maximum power density of 165 mW/m3, which is higher than that of MFC with MnO2 catalyst (95 mW/m3). The open circuit voltage (OCV) of the MFC operated with MnO2 cathode gradually decreased during 14 days of operation, whereas the MFC with Pt/MnO2 cathode remained almost constant throughout the operation suggesting the higher stability of the Pt/MnO2 catalyst. Therefore, Pt/MnO2 with 0.4 wt% Pt successfully demonstrated as an efficient and low cost electrocatalyst for ORR in air cathode MFC with higher electrochemical activity, stability and hence enhanced performance. Keywords—Microbial fuel cell, oxygen reduction reaction, Pt/MnO2, palm oil mill effluent, polarization curve. I.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Aisha Fatima, Liam Ryan, "Advanced Nanostructured Catalysts for Microbial Fuel Cells," Journal of Functional Materials, vol. 31, no. 6, pp. 28–34, 2024.

Serial: 7

The Impact of Cognitive Biases on Decision Making

Authors: Evelyn L. Brooks, Julian A. Thompson
Page No: 35–42
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Abstract not available.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Evelyn L. Brooks, Julian A. Thompson, "The Impact of Cognitive Biases on Decision Making," Journal of Functional Materials, vol. 31, no. 6, pp. 35–42, 2024.

Serial: 8

Emerging Trends in Hybrid Materials Science

Authors: Amane K. Patel, Elianore M. Jensen
Page No: 43–46
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—Nanotechnology in pristine sense refers to building of structures at atomic and molecular scale. Meticulously nanotechnology encompasses the nanomaterials with at least one dimension size ranging from 1 to 100 nanometres. Unlike the literal meaning of its name, nanotechnology is a massive concept beyond imagination. This paper predominantly deals with relevance of nanotechnology in automotive industries. New generation of automotives looks at nanotechnology as an emerging trend of manufacturing revolution. Intricate shapes can be made out of fairly inexpensive raw materials instead of conventional fabrication process. Though the current era have enough technology to face competition, nanotechnology can give futuristic implications to pick up the modern pace. Nanotechnology intends to bridge the gap between automotives with superior technical performance and their cost fluctuation. Preliminarily, it is an area of great scientific interest and a major shaper of many new technologies. Nanotechnology can be an ideal building block for automotive industries, under constant evolution offering a very wide scope of activity. It possesses huge potential and is still in the embryonic form of research and development. Keywords—Nanotechnology, nanomaterials, manufacturing, automotive industry. I.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Amane K. Patel, Elianore M. Jensen, "Emerging Trends in Hybrid Materials Science," Journal of Functional Materials, vol. 31, no. 6, pp. 43–46, 2024.

Serial: 9

Optimizing Building Information Modelling for Accurate Cost Estimation

Authors: Astrid Jensen, Ethan Patel
Page No: 47–52
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—Construction cost estimation is one of the most important aspects of construction project design. For generations, the process of cost estimating has been manual, time-consuming and error prone. This has partly led to most cost estimates to be unclear and riddled with inaccuracies that at times lead to over- or underestimation of construction cost. The development of standard set of measurement rules that are understandable by all those involved in a construction project, have not totally solved the challenges. Emerging Building Information Modelling (BIM) technologies can exploit standard measurement methods to automate cost estimation process and improve accuracies. This requires standard measurement methods to be structured in ontological and machine-readable format; so that BIM software packages can easily read them. Most standard measurement methods are still text-based in textbooks and require manual editing into tables or Spreadsheet during cost estimation. The aim of this study is to explore the development of an ontology based on New Rules of Measurement (NRM) commonly used in the UK for cost estimation. The methodology adopted is Methontology, one of the most widely used ontology engineering methodologies. The challenges in this exploratory study are also reported and recommendations for future studies proposed. Keywords—BIM, Construction projects, Cost estimation, NRM, Ontology. I.

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Year: 2024
Journal: Research Paper
Vol/Issue: 31 (6)
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Astrid Jensen, Ethan Patel, "Optimizing Building Information Modelling for Accurate Cost Estimation," Journal of Functional Materials, vol. 31, no. 6, pp. 47–52, 2024.
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